(B) the application of high chromium cast iron ball in gold molybdenum concentrator beneficiation plant genus ball high consumption, especially iron ore concentrator ball unit consumption is higher than abroad more than doubled, so the ball great consumption According to the statistics of relevant departments in China, in 1979, the domestic concentrating plant used about 240,000 tons of grinding balls in the whole year. Therefore, researching the material of grinding balls, improving and improving the performance of grinding balls and reducing the single consumption of grinding balls will start the national economy. Great energy saving effect. High chromium cast iron grinding ball chemical composition Chemical  learn   to make   Share ( % ) Hardness Rc Microstructure C Si Mn S P Cr Mo Cu Fe 2.4~2.5 ≤ 1.0 ≤ 0.8 ≤ 0.04 ≤ 0.04 15~16 1.0~1.2 0.8~1.0 margin ≥ 60 Martensite + eutectic carbide twelve-time carbide The casting process of the grinding ball is made by wet sand casting, and the atmospheric pressure side feeder is fed. The temperature of the tapping is 1450~1470°C, and 0.8% of the rare earth is added to the bag, and the pouring temperature is 1350~1360°C. Grinding ball heat treatment is kept at 980 ° C for two hours after the furnace temperature. Immediately after the furnace is released, the grinding ball is spread on the ground, air-cooled, and the surface hardness of the grinding ball is checked, generally Rc ≥ 60. Molybdenum ore mineral phase composition Mineral phase Black mica  Yunying Plagioclase Pyrite Potash feldspar Molybdenite other Mineral phase % 42.4 30.5 10.2 6.7 10.2 0.175   Mineral phase hardness HV 900-1200 840-1130 795 3. Test Results The consumption of forged steel balls used in Jinduicheng over the years is shown in the table below. The single-consumption measurement results and the wear rate measurement results of the high-chromium cast iron balls are shown in the next two tables. Jinduicheng forged steel grinding ball statistics Concentrator Statistical period Processing of minerals (tons) Forged steel ball consumption (tons) Wear kg/T Small selection plant 1966-1982 1863025.26 3285 1.764 Selected plant 1971-1982 15587646.42 25574.5 1.641 total   17450671.68 28859.5 1.654 Determination of single consumption of high cast iron grinding balls Date of measurement Operating period (tons) Processing of minerals (tons) High chrome ball consumption (kg) Grinding ball unit consumption (kg / ton) Remarks 1982.10.16 729 7357.78 3808.77 0.5176 Sampling calculation 1982.10.28 1009.75 10290.86 5164.186 0.5018 Sampling calculation 1982.11.29 1664.92 17017.08 7371.346 0.433 Sampling calculation 1982.12.25 2195.42 22,443.32 10771.346 0.48 Sampling calculation 1983.1.26 2784.09 28,304.67 13911 0.491 Clearance Determination of wear rate of high chromium cast iron grinding balls Determination date and runtime (hours) Ф100 Ф80 Ф60 Ball weight (g) Ball weight loss (g) Wear rate (g / hr) Ball weight (g) Ball weight loss (g) Wear rate (g / hr) Ball weight (g) Ball weight loss (g) Wear rate (g / hr) 82.9.11   4302.6     2186.38     71.2     82.10.16 729 3714 888.6 1.219 1751.6 44.78 0.596 614.75 56.45 0.352 82.11.28 280.75 3225 189 0.673 1575.63 175.99 0.627 547.9 66.85 0.238 82.11.29 655.17 2591.4 633.6 0.967 1205.4 370.23 0.565 404.5 143.4 0.219   530.5 2113.3 478.1 0.901 1000 205.4 0.387 316 88.5 0.167 82.9.11 588.67 1574.1 539.2 0.916 7421 257.9 0.438 200.8 115.2 0.19 83.1.26 2784.09   2728.5 0.98   1444.28 0.519   670.4 0.241 It can be seen from the tabular data that the use of high-chromium cast iron balls is only 0.491 kg/ton. Compared with the original consumption of 1.654 kg / ton of forged steel balls, the unit consumption is reduced by 70.3%. A high-chromium casting balloon can be used for 3.369 forged gold balls. According to the measurement, the crushing rate of the high chromium casting balloon is also very low. During the test, only three cracks were found in the ф100 mm ball, that is, the ball breaking rate was 0.67 ‰; and the ф80, ф60 mm balls were not found to have broken the ball. It can be seen that the high chromium cast balloon of the selected component has sufficient toughness to prevent the occurrence of broken ball.
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The Department of Mechanical Engineering of Xi'an Jiaotong University and Jinduicheng Molybdenum Co., Ltd. jointly carried out tests on the application of high- chromium cast iron balls in molybdenum beneficiation plants, and achieved remarkable results.
High chromium cast iron is characterized by its metallographic structure: high yield strength martensitic metal matrix with discontinuous high hardness (Fe, Cr) 7C3 carbide phase, so it is especially suitable for abrasive wear. High chromium cast iron flat plate in a coal grinding mill liner as the roll sleeve and has been quite successful, its life was 3 to 4 times the original high-manganese steel and 9 to 10 times. Used as a lining in cement mills, the wear is also greatly reduced. It shows that high cast iron has a broad prospect in the case of abrasive wear, but what is the effect of high chromium cast iron under wet grinding conditions? No domestic data reported in Japan recently reported high-chrome cast iron wet grinding of copper ore wear rate of 0.4997 g / hour, we can see, although wet grinding to reduce abrasion resistance, but the high chromium cast iron wear rate is still much lower.
1. Chemical composition casting process of high chromium cast iron balls The chemical composition of high cast iron balls is shown in the table.
Jinduicheng Molybdenum Co., Ltd. originally used medium carbon steel balls produced by Handan Iron and Steel Co., Ltd. The surface hardness of steel balls is Rc52~56, and the hardness of core is Rc34~36.
2. The molybdenum ore mineral composition andesite type metal ore, granite porphyry see small object molybdenite minerals, mineral and non-current quartz, potassium feldspar, plagioclase were interspersed with other symbiotic relationship, and its hardness In terms of minerals, the highest hardness quartz is 30.5%, and the composition of molybdenum ore is shown in the table below.
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According to preliminary estimates by the test unit, the use of high-chromium cast iron balls can save 8,000 tons of steel balls per year for the 10,000-tonne forged steel balls, saving the cost of steel balls by at least 1.2-1.8 million yuan.
The high-chromium cast iron ball has defects in the casting process, and has pores, shrinkage, etc., which makes the ball compact and the strength performance are reduced, and the defect is easily peeled off, and the wear is accelerated. Measures are currently being taken to improve the intrinsic quality of the ball.
November 18, 2019